Double Proton Transfer Across a Table: The Formic Acid Dimer–Fluorobenzene Complex
نویسندگان
چکیده
Mit Fluorbenzol als Nachbarmolekül können die Protonen des Ameisensäure-Dimers durch Quantentunneln transferieren, so wie sie es im reinen Ameisensäure-Dimer tun. einem kombinierten experimentellen und theoretischen Ansatz ermitteln Weixing Li, Denis S. Tikhonov Melanie Schnell in ihrer Zuschrift auf 25878 den folgenden Mechanismus: Das benachbarte beeinflusst nicht Reaktionsbarriere, sondern verringert Tunnelrate Doppelprotonentransfers Ameisensäure-Dimers. Die molekulare Betrachtung der Umstrukturierung Umgebung bei dieser Protonentransferreaktion ist ein Schritt zum Verständnis Reaktionen einer komplexen Umgebung.
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ژورنال
عنوان ژورنال: Angewandte Chemie
سال: 2021
ISSN: ['1521-3773', '1433-7851', '0570-0833']
DOI: https://doi.org/10.1002/ange.202112787